Journal
ORGANIC LETTERS
Volume 11, Issue 4, Pages 995-997Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8029438
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- Centre National de la Recherche Scientifique
- GlaxoSmithKline
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When allylamine is used as the amino input in Ugi-Smiles couplings of o-nitrophenols, the resulting adducts can be deallylated by a palladium-catalyzed process leading to a formal Ugi-Smiles coupling with ammonia. This new sequence, combined with hydrogenolysis of the nitro group, offers an interesting multicomponent entry to benzotriazole and benzimidazole scaffolds.
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