4.8 Article

Stereoselective DABCO-Catalyzed Synthesis of (E)-α-Ethynyl-α,β-Unsaturated Esters from Allenyl Acetates

Journal

ORGANIC LETTERS
Volume 11, Issue 6, Pages 1445-1448

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol9001703

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Funding

  1. Korea Science and Engineering Foundation (KOSEF)
  2. Ministry of Science and Technology [M10600000203-06J0000-20310]
  3. Korea Sanhak Foundation
  4. National Research Foundation of Korea [2006-0052329, 핵09A3015] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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(E)-alpha-Ethynyl-alpha,beta-unsaturated esters were exclusively prepared in good to excellent yields from treatment of allenyl acetates with 10 mol % DABCO in DMF at room temperature.

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