Journal
ORGANIC LETTERS
Volume 11, Issue 20, Pages 4624-4627Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901901m
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Funding
- University of Florida
- Herman Frasch Foundation [647-HF07]
- Petroleum Research Fund [47539-G1]
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Furans, pyrroles, and thiophenes are efficiently prepared by gold-catalyzed dehydrative cyclizations of readily available, heteroatom-substituted propargylic alcohols. The reactions are rapid, high-yielding, and procedurally simple, giving essentially pure aromatic heterocycles in minutes under open-flask conditions with catalyst loadings as low as 0.05 mol %.
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