Journal
ORGANIC LETTERS
Volume 11, Issue 21, Pages 4962-4965Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902116b
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- Fulbright Foreign Student Program
- National Institute of General Medicine [GM-60578]
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The resting state of the gold(I)-catalyzed hydroarylation of 1 changes In the presence of Ag+, with silver free catalysts resting at the dinuclear gold structure 5 and Ag+ containing solutions resting at a heteronuclear species like 6. Adventitious Ag+ (typically from LAuCl activation) can therefore intercept key organogold intermediates and effect the catalysis even when it does not effect the reaction in Au free control experiments.
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