Journal
ORGANIC LETTERS
Volume 11, Issue 11, Pages 2293-2296Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900609f
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- EPSRC
- European Regional Development Fund (ERDF).
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Aryl-substituted N-tosyl alkynyl aziridines undergo a gold-catalyzed ring expansion to afford 2,5-substituted pyrrole products. Under certain conditions, a ring-expansion and rearrangement leads to 2,4-substituted pyrroles. The reaction pathway is determined by the counterion to the gold catalyst.
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