Journal
ORGANIC LETTERS
Volume 11, Issue 7, Pages 1507-1510Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900110g
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Funding
- National Natural Science Foundation of China [20572105, 20621061]
- National Basic Research Program of China [2006CB922003]
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A mild and facile process for the preparation of 1,4-fullerenols C60ArOH was achieved. The key intermediate 1,2-C60Ar(NO2) was identified to better understand the reaction mechanism. Further functionalizations including esterification, etherification, and arylation of the synthesized 1,4-C60ArOH provided efficient access to versatile fullerene derivatives in the presence of p-toluenesulfonic acid.
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