Journal
ORGANIC LETTERS
Volume 11, Issue 15, Pages 3462-3465Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901297s
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Funding
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft
- Deutsche Krebshilfe
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In contrast to the formation of C-O and C-N bonds it was only recently that the selective C-S bond formation by means of transition metal complexes moved more into the center of research. This is somewhat surprising given the fact that the sulfur atom in a functional group can possess different oxygenation levels which correspond to different chemical properties and reaction portfolios, Herein we wish to communicate a regioselective Fe-catalyzed allylic sulfonation that allows for the preparation of various chiral aryl allyl sulfones In good to excellent yields.
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