Journal
ORGANIC LETTERS
Volume 11, Issue 14, Pages 3020-3023Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901022g
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The intense blue fluorescence of the infusion of Lignum nephriticum (Eysenhardtia polystachya), first observed in the sixteenth century, is due to a novel four-ring tetrahydromethanobenzofuro[2,3-d]oxacine which is not present in the plant but is the end product of an unusual, very efficient iterative spontaneous oxidation of at least one of the tree's flavonoids.
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