Journal
ORGANIC LETTERS
Volume 11, Issue 2, Pages 341-344Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802542c
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Following an A -> ABC strategy, a new synthesis of 6-oxa-allocolchicinoids was developed exploiting a microwave-promoted Co- or Rh-catalyzed intramolecular [2 + 2 + 2]-cycloaddition (alkyne cyclotrimerization) as a key step. The approach opens a short and efficient access to a variety of novel compounds, some of which were found to exhibit significant and selective apoptosis-inclucing activities against BJAB tumor cells.
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