4.8 Article

Arylation and Vinylation of α-Diazocarbonyl Compounds with Boroxines

Journal

ORGANIC LETTERS
Volume 11, Issue 7, Pages 1667-1670

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol900362d

Keywords

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Funding

  1. Natural Science Foundation of China [20832002, 20772003, 20821062]
  2. National Basic Research Program of China [2009CB825300]
  3. MOE of China

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An alternative approach for alpha-arylation and alpha-vinylation of carbonyl compounds is described: reaction between aryl- or vinylboroxines with alpha-diazocarbonyl compounds leads to the formation of alpha-arylated or alpha-vinylated carbonyl compounds under mild conditions.

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