4.8 Article

Diastereodivergent Addition of Allenylzincs to Aryl Glyoxylates

Journal

ORGANIC LETTERS
Volume 11, Issue 11, Pages 2397-2400

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol900494g

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Funding

  1. Tibotec

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A diastereodivergent addition of allenylzincs to aryl glyoxylates was observed depending on the method used for the preparation of the allenylzinc reagent. The allenylzincs were prepared from propargylic benzoates in the presence of a palladium catalyst or by metalation of alkynes.

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