Journal
ORGANIC LETTERS
Volume 11, Issue 23, Pages 5426-5429Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902271b
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Funding
- MEXT, Japan [21685011]
- Iketani Science and Technology Foundation
- Ministry of Education, Science, and Technology of Korea [2008-8-1955]
- AFSOR/AOARD
- Ministry of Education, Science & Technology (MoST), Republic of Korea [R32-2008-000-10217-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [2009-0093839, 과06A1503] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- Grants-in-Aid for Scientific Research [21685011] Funding Source: KAKEN
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Treatment of perylene bisimide (PBI) with various arylboronates In the presence of a ruthenium catalyst provides tetraarylated PBIs at 2,5,8,11-positions in good yields with perfect regioselectivity. The electronic nature of the introduced aryl substituents has a significant impact on their optical and electronic properties. This protocol has been applied to the synthesis of a water-soluble emissive PBI derivative.
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