Journal
ORGANIC LETTERS
Volume 11, Issue 12, Pages 2711-2714Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900962v
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- Ministry of Education, Culture, Sports, Science, and Technology of Japan
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Treatment of olefins bearing a directing group with alpha,beta-unsaturated carbonyl compounds, alkynes, or aldehydes in the presence of a catalytic amount of a rhenium complex, [ReBr(CO)(3)(thf)](2) gave gamma,delta-unsaturated carbonyl compounds, dienes, and allyl silyl ethers, respectively. This reaction proceeds via C-H bond activation, insertion of unsaturated molecules into the formed rhenium-carbon bond, and then reductive elimination (or transmetalation in the case of aldehydes).
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