4.8 Article

Cu2+ Ion-Induced Self-Assembly of Pyrenylquinoline with a Pyrenyl Excimer Formation

Journal

ORGANIC LETTERS
Volume 11, Issue 15, Pages 3378-3381

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol901221q

Keywords

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Funding

  1. SRC (KOSEF) [R11-2005-008-00000-0]
  2. MEST
  3. KOSEF [R01-2006-10696]
  4. Korea Institute of Science and Technology Information [KSC-2007-S00-0018]
  5. National Research Foundation of Korea [과09A1514, 2009-0081566, 2008-0057799] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Synthesis of a novel pyrene derivative sensor (1) and its intermolecular binding pattern to Cu2+ in CH3CN were investigated. Upon Cu2+ binding, the sensor exhibited a strong static excimer emission at 460 nm, along with a weak monomer emission at 388 nm. The excimer emission intensity induced by the Cu2+ ion declined as the spacer length between the pyrene and quinolinylamide unit increased. The Cu2+ ion-induced self-assembled pyrenyl excimer formation is rationalized by fluorescence experiments and theoretical DFT calculations.

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