Journal
ORGANIC LETTERS
Volume 11, Issue 8, Pages 1705-1708Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9002724
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- CSIR-New Delhi
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A highly stereoselective total synthesis of amphiclinolide T1 is achieved using Sharpless asymmetric epoxidation, base-induced epoxide opening, radical cyclization, diastereoselective reduction followed by allylation, Evans methylation, base-induced reductive elimination, umpolung reaction, chemoselective oxidation, and regioselective macrolactonization.
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