☆ 4.8 Article

A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates

ORGANIC LETTERS (2009)

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Journal

ORGANIC LETTERS
Volume 11, Issue 14, Pages 3140-3142

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol901031b

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Categories

Chemistry, Organic

Funding

  1. Pfizer Inc

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A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed.

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