Journal
ORGANIC LETTERS
Volume 11, Issue 20, Pages 4596-4599Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901870n
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Funding
- American Cancer Society [RSG-06-117-01]
- Boehringer Ingelheim, Eli Lilly Co.
- National Institutes of Health NIGMS [GM80266]
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A procedure for the coupling of aliphatic imines with allylic and allenic alkoxides is described. The success of these studies was enabled by a unique reactivity profile of Ti(IV) isopropoxide/n-BuLi compared to well-known Ti(IV) isopropoxide/RMgX systems.
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