Journal
ORGANIC LETTERS
Volume 11, Issue 21, Pages 4850-4853Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901923x
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- National Institutes of Health [CA-59703]
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An acid-promoted glycosylation and alkynol cycloisomerization sequence provided direct access to the 2-deoxytrisaccharide corresponding to the fucose-saccharosamine-digitoxose substructure of saccharomicin B. In the course of this work, the absolute stereochemistry of the repeating fucose-saccharosamine disaccharide of saccharomicins was also confirmed.
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