Journal
ORGANIC LETTERS
Volume 11, Issue 10, Pages 2201-2204Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9005618
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Funding
- Canada Research Chair Program
- Natural Sciences and Engineering Research Council of Canada
- Canada Foundation for Innovation
- Merck Frosst Centre for Therapeutic Research
- Fonds de recherche sur la nature et les technologies
- Universite Laval
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The use of 5,5(dimethyl)-i-Pr-PHOX as a practical equivalent of t-Bu-PHOX in asymmetric catalysis is reported. This new member of the phosphinooxazoline (PHOX) ligand family behaves similarly in terms of stereoinduction to t-Bu-PHOX with the key advantage of being readily accessible as both enantiomers starting from either (S)- or (R)-valine.
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