Journal
ORGANIC LETTERS
Volume 11, Issue 15, Pages 3510-3513Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901366q
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- Ministry of Education, Culture, Sports, Science and Technology, Japan
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We report iridium-catalyzed coupling of 2-alkynes such as 1-aryl-1-propynes with primary alcohols leading to secondary homoallylic alcohols as products. This reaction involves an iridium-catalyzed novel catalytic transformation of 2-alkynes and primary alcohols through the formation of hydrido(pi-allyl)iridium as a possible key intermediate.
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