Journal
ORGANIC LETTERS
Volume 11, Issue 2, Pages 481-483Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802665v
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- NIH [GM 58832]
- China scholarship council
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Enamides were efficiently prepared via a novel Rh/C-catalyzed direct hydroacylation of ketoximes. Up to 88% isolated yield of enamides were obtained with this method. Subsequent asymmetric hydrogenation of the enamides with Rh/DuanPhos complex gave the corresponding chiral amine in excellent enantioselectivities (up to 99.7% ee).
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