Journal
ORGANIC LETTERS
Volume 11, Issue 22, Pages 5098-5101Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9022694
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- German Research Foundation (DFG)
- Fonds der Chemischen Industrie
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Carbohydrate-functionalized oligothiophenes have been synthesized applying mild Sonogashira cross-coupling conditions. In an aqueous environment the amphiphilic hybrids self-assemble into chiral superstructures as a result of multiple hydrogen bond interactions and the helicity of the aggregates is controllable by the configuration of the carbohydrate unit. By means of atomic force microscopy highly ordered layer arrangements on substrates were characterized.
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