Journal
ORGANIC LETTERS
Volume 11, Issue 18, Pages 4136-4138Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901608k
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Funding
- NSFC [20625204, 20632030, 90713007, 20772141]
- MOST_863 [2006AA09Z405, 2006AA09Z446]
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A new and efficient samarium diiodide-promoted carbon-carbon bond fragmentation reaction of alpha-aminomethyl malonates, taking place normally at room temperature and generating the corresponding deaminomethylation products in 74-94% yields, is reported. The presence of the amino group is necessary for the success of the current transformation.
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