Journal
ORGANIC LETTERS
Volume 11, Issue 17, Pages 3866-3869Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901474u
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Funding
- National Science Foundation
- Petroleum Research Fund
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0840995] Funding Source: National Science Foundation
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Photolysis of fluorophenyldiazirine, incarcerated in hemicarcerand 2, affords fluorophenylcarbene, which attacks an aryl unit of the host, leading (after rearrangement) to a fluoromethoxy/phenyltropone derivative of the hemicarcerand. The Incarcerated carbene is probably unstable at temperatures above 100 K.
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