Journal
ORGANIC LETTERS
Volume 11, Issue 18, Pages 4064-4067Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901505e
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- National Science Council of the Republic of China, Taiwan [NSC 97-2113-M-029-004]
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An oxazabicycle and an oxazatricycle were efficiently synthesized by coupling of coumarins and N-alkylquinolium or isoquinolium salt to investigate their fluorescence redox-switching properties. Chemical reduction of the strongly fluorescent oxazabicycle and oxazatricycle results in the ring-opened products with a distinct decrease in emission intensity. Both resulting ring-opened species can be swiftly reverted to the original ring-closed forms by oxidation.
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