4.8 Article

A Concise Approach to the Synthesis of opp-Dibenzoporphyrins through the Heck Reaction

Journal

ORGANIC LETTERS
Volume 11, Issue 19, Pages 4251-4253

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol901615f

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Funding

  1. NSF [0722547]
  2. Miami University
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [0722547] Funding Source: National Science Foundation
  5. Direct For Mathematical & Physical Scien
  6. Division Of Chemistry [0839233] Funding Source: National Science Foundation

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A concise approach to the synthesis of functionalized opp-dibenzoporphyrins is described. In this method, introduction of alkenyl groups to the porphyrin periphery through the vicinal 2-fold Heck reaction, 6-pi electrocyclization, and subsequent aromatization occur in one pot.

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