Journal
ORGANIC LETTERS
Volume 11, Issue 15, Pages 3290-3293Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901046z
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Funding
- National Institute of General Medical Sciences of the National Institutes of Health [GM-61066]
- National Science Foundation [CHE-0315572]
- Eli Lilly
- National Institute of General Medical Sciences for a postdoctoral fellowship [GM-085910]
- Direct For Mathematical & Physical Scien [0848121] Funding Source: National Science Foundation
- Division Of Chemistry [0848121] Funding Source: National Science Foundation
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The cyclization of gamma,delta-unsaturated tertiary hydroperoxides in the presence of a palladium(II) catalyst afforded 1,2-dioxanes resembling biologically active natural products. A variety of substrates were screened, and synthetic manipulations were accomplished to construct compounds with structural similarity to antimalarial targets.
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