4.8 Article

Synthesis, Polymerization, and Unusual Properties of New Star-Shaped Thiophene Oligomers

Journal

ORGANIC LETTERS
Volume 11, Issue 15, Pages 3230-3233

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol901127q

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Funding

  1. NSERC
  2. CFI
  3. PBEEE

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Terthienobenzene (TTB, 6) was prepared through a new, high yield route along with pi-extended derivatives 10 and 11. Electropolymerization of tris-EDOT derivative 11 results in a highly stable cross-linked conjugated polymer that shows polaron confinement between the TTB units as confirmed by UV-vis-NIR spectroelectrochemistry and EPR.

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