Journal
ORGANIC LETTERS
Volume 11, Issue 15, Pages 3350-3353Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9012052
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Funding
- National Natural Science Foundation of China [20604020, 20702048, 20774086, 20834004, J0830413]
- National Basic Research Program [2009CB930104]
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Taco complex templation based on the bis(m-phenylene)-32-crown-10/paraquat recognition motif is used to develop a general method for preparing mechanically interlocked molecules. A [2]rotaxane and a [2]catenane were synthesized in high yields by a ring-closing metathesis reaction, which was owed to the impactful template effect. Due to the high symmetry of (5,5')-difunctional bis(m-phenylene)-32-crown-10 derivatives, this taco complex templated synthesis has potential to be a tempting method to solve a symmetry-based problem In the fabrication of complicated mechanically interlocked structures.
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