Journal
ORGANIC LETTERS
Volume 11, Issue 15, Pages 3414-3417Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901241s
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Funding
- Korea Research Foundation [KRF-2006-312-C00587]
- Center for Intelligent Nano-Bio Materials at Ewha Womans University
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The in situ generated Blaise reaction intermediate, a zinc bromide complex of beta-enaminoester, reacts with various unactivated terminal alkynes and an internal alkyne under mild conditions to afford alpha-vinylated beta-enaminoesters in good to excellent yields.
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