Journal
ORGANIC LETTERS
Volume 11, Issue 14, Pages 2980-2983Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9009865
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Funding
- Peking University
- National Science Foundation of China [20702002, 20872003]
- National Basic Research Program of China [2009CB825300]
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A ligand-free Pd-catalyzed highly selective oxidative Heck reaction of organoboronic acids with allyl esters was developed. beta-H elimination is highly chemoselectively controlled, leading to gamma-substituted allyl esters, which is contrary to the traditional Heck-type reactions of allyl esters. Moreover, the regio- and stereoselectivities are also high due to the chelation between O and Pd atoms.
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