Journal
ORGANIC LETTERS
Volume 11, Issue 11, Pages 2225-2228Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9001834
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Funding
- National Science Foundation [CHE-0641523]
- New York State Office of Science, Technology, and Academic Research (NYSTAR).
- Chemical Sciences, Geosciences and Biosciences Division, Office of Basic Energy Sciences, US DOE [DE-FG02-01ER15264]
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Contorted hexabenzocoronenes (HBCs) have been synthesized in an expedited manner utilizing a double Barton-Kellogg olefination reaction and a subsequent Scholl cyclization. The scope of both transformations was investigated using a series of pentacene quinones and double olefin precursors. The utility,of these reactions to help create functionalized and oligomeric HBCs in a rapid manner is demonstrated.
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