Journal
ORGANIC LETTERS
Volume 11, Issue 13, Pages 2868-2871Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900739x
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- Ecole Polytechnique
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The radical reaction of TMS-substituted xanthates with 2,2-dichlorovinyl ethyl sulfone afforded TMS-substituted homodichlorovinyl compounds that can be transformed into TMS-substituted propargyl alcohols. Various 2,3-allenols were efficiently prepared from the reaction of these TMS-substituted propargyl alcohols with TBAF.
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