Journal
ORGANIC LETTERS
Volume 11, Issue 13, Pages 2856-2859Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901081a
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- NIGMS [GM72586]
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A triazolinylidene carbene catalyzed intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides has been developed. 1,4-Dicarbonyl products are afforded in good to excellent yields, enantioselectivities, and diastereoselectivities. Further derivatization of the products affords useful intermediates for organic synthesis.
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