Journal
ORGANIC LETTERS
Volume 11, Issue 12, Pages 2491-2494Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900843a
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- EPSRC
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The rhodium-catalyzed 1,4-addition of arylboronic acids to an enantiopure heterocyclic acceptor proceeds under ligand control to effect an asymmetric synthesis of functionalized pyrrolizidinones. The protocol allows convenient access to all four stereoisomers of pyrrolizidinone 3a (Ar = Ph) by appropriate selection of substrate and catalyst.
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