4.8 Article

Transition-Metal-Free Carboxylation of Organozinc Reagents Using CO2 in DMF Solvent

Journal

ORGANIC LETTERS
Volume 11, Issue 9, Pages 2035-2037

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol900528h

Keywords

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Funding

  1. Advanced Molecular Transformations of Carbon Resources [19020005]
  2. Synergistic Effects for Creation of Functional Molecules [20036007]
  3. Ministry of Education, Science, Sports and Culture, Japan [19390002, 1865900]
  4. Yamada Science Foundation
  5. Grants-in-Aid for Scientific Research [19390002, 19020005] Funding Source: KAKEN

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An efficient process for the carboxylation of functionalized organozinc reagents with CO2 under transition-metal-free conditions was developed by employing DMF solvent in the presence of LICl.

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