Journal
ORGANIC LETTERS
Volume 11, Issue 1, Pages 145-147Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802571d
Keywords
-
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Global COE (Center of Excellence) Program
- Global Education and Research Center for Bio-Environmental Chemistry at Osaka University
Ask authors/readers for more resources
The first clear differentiation on deslipping rates affected by the difference in the diastereomeric stereocenters of rotaxanes up to 8.4 times and unexpectedly large steric kinetic isotope effect on the deslipping reaction (ca. 20%) were observed. On the basis of the kinetic parameters, steric kinetic isotope effect, and H-1 NMR spectra of the nondeuteriated and deuteriated rotaxanes, we propose a deslipping mechanism involving pre-equilibrium.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available