Journal
ORGANIC LETTERS
Volume 11, Issue 4, Pages 887-890Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802887h
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- NIH [GM-43214]
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The development of one-pot imine formation and asymmetric Pictet-Spengler reactions cocatalyzed by a chiral thiourea and benzoic acid is described. Optically active tetrahydro-beta-carbolines, ubiquitous structural motifs in biologically active natural products, are obtained in high ee directly from tryptamine and aldehyde precursors.
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