Journal
ORGANIC LETTERS
Volume 11, Issue 11, Pages 2321-2324Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900680f
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Funding
- JSPS, KAKENHI [20245022]
- MEXT [19750072, 21750094]
- Toray Science Foundation
- Shorai Foundation for Science and Technology
- Grants-in-Aid for Scientific Research [21750094, 21200033, 20245022, 19750072] Funding Source: KAKEN
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A catalytic enantioselective Strecker reaction catalyzed by novel chiral lanthanum(III)-binaphthyl disulfonate complexes was developed. The key to promoting the reactions was a semistoichiometric amount of AcOH or i-PrCO2H, which takes advantage of HCN generation in situ. The corresponding cyanation products were obtained in high yields and with high enantioselectivities.
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