4.8 Article

Synthesis of meso-Polyphosphorylporphyrins and Example of Self-Assembling

Journal

ORGANIC LETTERS
Volume 11, Issue 17, Pages 3842-3845

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol901421e

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Funding

  1. ARCUS 2007 Burgundy-Russia project
  2. Russian Foundation for Basic Research
  3. CNRS
  4. European Research Association Suprachem

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Pd-catalyzed coupling reactions have been used to prepare meso-phosphorylporphyrins, A 2D metal-organic network formed via P=O center dot center dot Zn axial supramolecular coordination of 5,15-bis(diethoxyphosphoryl)-10,20-diphenylporphyrin is the first example of a 2D framework based on phosphorylporphyrin derivatives.

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