Journal
ORGANIC LETTERS
Volume 11, Issue 23, Pages 5538-5541Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902364d
Keywords
-
Categories
Funding
- NIH [GM038436, GM026782]
- Ministere des Affaires Etrangeres et Europeennes (France)
Ask authors/readers for more resources
Density functional theory was used to locate transition states for hydroboration reactions of allenes with 9-borabicyclo[3.3.1]nonane and 10-R-9-borabicyclo[3.3.2]decane, as well as transition states for [1,3]-boratropic shift and aldehyde addition reactions of the derived allylboranes. The origin of kinetic versus thermodynamic control in the allene hydroboratlon step Is described.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available