Journal
ORGANIC LETTERS
Volume 11, Issue 12, Pages 2599-2602Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900955q
Keywords
-
Categories
Funding
- National Science Foundation [CHE 0616442]
Ask authors/readers for more resources
A small, axially chiral diacid was designed with chiral memory based on restricted rotation. Heating a racemic sample with a chiral alkaloid led to an enantiomeric excess of up to 40% ee. The guest-induced chirality was preserved on cooling to rt, which was maintained even in the absence of guest (t(1/2) = 14y). The chiral enrichment process was also reversible, allowing the diacid to be used as a chiral switch.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available