Journal
ORGANIC LETTERS
Volume 11, Issue 16, Pages 3622-3625Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol901400m
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Funding
- Chinese Academy of Sciences
- National Natural Science Foundation of China [20873166, 20625308]
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A novel series of chiral tetradentate N-4 ligands together with their manganese complexes have been designed and synthesized. With 1 mol% manganese catalyst loading, the enantioselective epoxidation of olefins proceeds with nearly full conversion and enantiomeric excess values of up to 89% for the first time.
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