Journal
ORGANIC LETTERS
Volume 11, Issue 6, Pages 1289-1292Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9000679
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Funding
- Department of Science and Technology, New Delhi [SR/S1/RFPC-10/2006]
- MHRD
- DRDO
- CSIR
- UGC, New Delhi
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The green emission defect (GED) produced by fluorenones has significantly retarded the commercial scope of fluorene-based B-OLEDs. In this paper, for the first time, it is demonstrated that the green light emitting fluorenones 7 can be converted to blue light emitting fluorenones 10 by appropriate positioning of donor-acceptor and chromophoric groups onto the fluorene/fluorenone backbone. Additionally, we report an elegant highly rapid synthetic route for donor-acceptor fluorenes and fluorenones at room temperature with excellent yields.
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