Journal
ORGANIC LETTERS
Volume 11, Issue 4, Pages 1023-1026Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802970g
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- EPFL
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The first catalytic method for the cyclization of vinyl-cyclopropyl ketones (formal homo-Nazarov reaction) is reported. Starting from activated cyclopropanes, heterocyclic, and carbocyclic compounds were obtained under mild conditions using Bronsted acid catalysts. Preliminary investigation of the reaction mechanism indicated a stepwise process.
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