Journal
ORGANIC LETTERS
Volume 11, Issue 12, Pages 2707-2710Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900941t
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Funding
- Chinese Academy of Science
- National Natural Science Foundation of China [20821002, 20872155]
- National Basic Research Program of China [73-2009CB825300]
- Shanghai Municipality [08PJ1411600]
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A novel palladium-catalyzed intramolecular aerobic oxidative allylic C-H amination of olefins has been developed. Bronsted base can modulate the regioselectivity, favoring the formation of 7-membered rings. Mechanistic studies using deuterium-labeled substrates as probes support a rate-determining allylic C-H activation/irreversible reductive elimination pathway.
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