Journal
ORGANIC LETTERS
Volume 11, Issue 7, Pages 1619-1622Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol900285w
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The first de novo synthesis of a beta-C-naphthyl glycoside displaying a convenient functionality for subsequent transformations into complex C-aryl glycosides is reported. The synthesis of this (+/-)-beta-C-1,5-dibenzyloxynaphthyl 6,6,6-trifluoro-3-amino glycoside relies on a hyperbaric HDA reaction involving a new 2-vinylnaphthalenic dienophile.
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