Journal
ORGANIC LETTERS
Volume 11, Issue 4, Pages 919-921Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8028803
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- Royal Institute of Technology
- Swedish Research Council
- Knut and Alice Wallenberg foundation
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The first example of asymmetric Lewis acid mediated [1,2]-rearrangement of N-benzylic proline amides to form quaternary proline derivatives is reported. The presented reaction is shown to proceed with remarkable high C-N-C chirality transfer. Various quaternary proline derivatives have been prepared in good to excellent yields and high enantiomeric purity.
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