4.8 Article

A Soluble and Stable Quinoidal Bisanthene with NIR Absorption and Amphoteric Redox Behavior

Journal

ORGANIC LETTERS
Volume 11, Issue 21, Pages 4854-4857

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol902241u

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Funding

  1. NRF Competitive Research Program [R-143-000-360-281]
  2. NUS Young Investigator Award [R-143-000-356-101]

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A soluble and stable quinoidal bisanthene (3) was synthesized, and it exhibited high molar absorptivity in the near-IR spectral region. In addition, compound 3 also showed good electrochemical amphotericity with four reversible one-electron transfer steps. Compound 3 represents a rare example of soluble and stable pi-conjugated polycyclic hydrocarbons with quinoidal character.

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