Journal
ORGANIC LETTERS
Volume 11, Issue 22, Pages 5278-5281Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902233r
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Funding
- Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
- National Basic Research Program of China [2009CB825300]
- National Natural Science Foundation of China [20872162, 20672127, 20732008, 20821002, 20702013]
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Catalyzed by Pd(II)/p-BQ, a tandem cycloisomerization and oxidation of arylvinylcyclopropenes took place smoothly to produce methyleneindene derivatives stereoselectively in moderate to excellent yields, affording an unusual example of solo addition by p-hydroquinone generated by oxidation of Pd(0) to Pd(II) along with the formation of a new C-O bond.
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